Hydrothermal synthesis and crystal structure of polytris (μ 2 - cis -1, 4–cyclohexanedicarboxylato) -κ 2 O: O ′ ] -bisμ 3 -1, 3, 5-tris[ (1 H -imidazol-1-yl) methylbenzene-κ 3 N, N ′, N ″ ]trizinc (II) trihydrate, C 60 H 72 N 12 O 15 Zn 3

Puntos clave

• The study aims to characterize the crystal structure of a tris-zinc complex synthesized using hydrothermal methods.
• Synthesis of poly{tris(μ2-cis-1,4–cyclohexanedicarboxylato)-κ2O:O′]-bis[μ3-1,3,5-tris[(1H-imidazol-1-yl)methyl]benzene-κ3N,N′,N″]trizinc(II) in hydrothermal conditions.
• X-ray diffraction analysis performed to determine crystal structure and parameters.
• Characterization of the compound at a temperature of 293 K.
• The compound crystallizes in a trigonal structure with R32 symmetry.
• Unit cell dimensions were found to be a = 17.9308(7) Å and c = 36.533(2) Å.
• Calculated volume of the crystal is 10172.2(10) Å3.