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February 21, 2026Next Materials0 citationsOpen Access

Thermal behaviour of organic PCMs with dispersed GNP nanoparticles

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MKM. Murali KrishnaSSShweta SinghASArun Kumar Sharma

Key Points

  • The study aims to evaluate the thermal behaviour and stability of organic phase change materials reinforced with graphene nanoplatelets.
  • Analyzed thermal conductivity of four organic PCMs reinforced with varying GNP concentrations.
  • Conducted FTIR analysis to assess chemical stability of PCMs.
  • Performed TGA and DTG analyses to evaluate thermal degradation properties.
  • GNP reinforcement delayed thermal degradation onset by 10–20°C across all composites.
  • Soya Wax with 0.5% GNP showed an increase in peak degradation temperatures.
  • Up to a 22% enhancement in thermal conductivity was observed with 0.5% GNP addition.

Abstract

To ensure efficient thermal energy storage, phase change materials (PCMs) must exhibit thermal and chemical stability. This study investigates four organic PCMs Soya Wax, Bee Wax, PEG, and Camphene reinforced with graphene nanoplatelets (GNPs) at 0.1 %, 0.3 %, and 0.5 % wt. Thermal conductivity analysis are carried out. FTIR analysis confirmed no significant chemical alteration upon GNP addition. TGA results showed a 10–20°C delay in thermal degradation onset across all composites. Soya Wax with 0.5 % GNP exhibited an increase in onset and peak degradation temperatures from 310 °C to 325 °C and 388 °C to 401 °C, respectively. DTG analysis indicated reduced degradation rates and broader profiles, while residual mass at 450 °C increased, signifying enhanced thermal resistance. These results confirm that GNP reinforcement improves the thermal durability of organic PCMs for energy storage applications. • Investigated thermal behaviour of GNP-reinforced organic PCMs. • Novel composite PCMs developed using Soya, Bee Wax, PEG, and Camphene. • GNPs enhanced thermal stability without altering PCM chemical structure. • Up to 22 % rise in thermal conductivity observed with 0.5 % GNP addition. • Improved degradation resistance confirmed through TGA and DTG analysis.

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Cite This Study

Krishna et al. (2026) studied this question.

synapsesocial.com/papers/69994aab873532290d01f0behttps://doi.org/10.1016/j.nxmate.2026.101761
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