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February 21, 2026Journal of Structural Chemistry0 citations

A Series of Molybdenum Halide Cluster Complexes with Acrylate and Metacrylate Ligands

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NVN. A. VorotnikovaKOK. O. OlawoyinABA. S. Berezin

Key Points

  • The aim is to synthesize and characterize molybdenum cluster complexes with specific organic ligands.
  • Synthesis of cluster complexes using (Bu4N)2[Mo6X8X6] and silver salts of respective acids.
  • Characterization using powder and single crystal X-ray diffraction, elemental analysis, IR and NMR spectroscopy.
  • Analysis of luminescent properties and photophysical parameters.
  • Successfully synthesized molybdenum cluster complexes with acrylate and metacrylate ligands.
  • Characterization techniques confirm the structure of the complexes.
  • Luminescent properties exhibited, indicating possible applications in photonic materials.

Abstract

We present the results of the synthesis and analysis of a series of organic-soluble cluster complexes of molybdenum: (Bu4N)2Mo6X8L6 (X = Br, I; L = –CH2=CH–COO– (acrylate, Acr–) and –CH2=C(CH3)–COO– (metacrylate, MAcr–)). The complexes are obtained by interacting (Bu4N)2Mo6X8X6 with silver salt of the respective acid. The mentioned compounds are characterized in detail by powder and single crystal X-ray diffraction, elemental analysis, IR and NMR spectroscopy. The luminescent properties and photophysical parameters of the solid cluster complexes are studied.

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Cite This Study

Vorotnikova et al. (2026) studied this question.

synapsesocial.com/papers/69994ba9873532290d01fd79https://doi.org/10.1134/s0022476626010208
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