Coordination compounds based on a phosphonic diamide-TEMPO diradical and CuII , NdIII , EuIII and TbIII ions: synthesis, magnetic properties and application in the aerobic oxidation of allylic and benzylic alcohols

Puntos clave

• The study aims to synthesize and evaluate the properties of coordination compounds involving a phosphonic diamide-TEMPO diradical and various metal ions.
• Synthesis of phenylphosphonic diamide bis-TEMPO diradical and metal complexes
• Structural characterization using spectroscopic techniques
• Assessment of magnetic properties
• Evaluation of catalytic activity in aerobic oxidation reactions
• Novel coordination compounds with distinct magnetic properties were formed
• The synthesized compounds effectively catalyzed the oxidation of allylic and benzylic alcohols
• Metal ions influence the magnetic behavior and catalytic efficiency of the compounds