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February 26, 2026Organic Chemistry Frontiers0 citations

Group 14 heavier 1,4-dimetallabenzenes: Influence of Aromaticity, Open-Shell Character and Strain on Small Molecule Activation

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DGDaniel González-PinardoIFIsrael Fernandez

Key Points

  • The aim is to understand how aromaticity, diradical character, and strain influence the reactivity of Group 14 heavier 1,4-dimetallabenzenes.
  • Utilized quantum-chemical calculations to analyze Group 14 heavier 1,4-dimetallabenzenes
  • Evaluated the effects of aromaticity, diradical character, and strain on reactivity
  • Identified specific activation patterns for small molecules
  • Demonstrated that both strain and diradical character significantly influence reactivity
  • Showed varying aromaticity affects the behavior of compounds

Abstract

The influence of the aromaticity, diradical character and strain on the reactivity of Group 14 heavier 1,4-dimetallabenzenes (E = Si, Ge, Sn) has been investigated using quantum-chemical calculations. To this...

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Cite This Study

González-Pinardo et al. (2026) studied this question.

synapsesocial.com/papers/699f95ba1bc9fecf3dab3e49https://doi.org/10.1039/d6qo00006a
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