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February 27, 2026Chemical Science0 citationsOpen Access

Influence of Aliovalent Substitution on Structure and Dynamics in Sodium Halide Na 3-2x Y 1-x Nb x Cl 6 Solid Electrolytes

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BPBrian PhanTSTso ShuenDVDmitry Vrubleskiy

Key Points

  • The central aim is to understand how aliovalent substitution alters the structure and dynamics of sodium halide solid electrolytes.
  • Characterization of sodium halide solid electrolytes with varying amounts of aliovalent ions.
  • Analysis of structural changes using X-ray diffraction and spectroscopic methods.
  • Evaluation of dynamic properties through ionic conductivity measurements.
  • Aliovalent substitution significantly alters the structural framework of the electrolytes.
  • Changes in ionic conductivity were observed with different levels of aliovalent ions.
  • Improvement in overall electrolyte stability was noted.

Abstract

Sodium halide solid electrolytes are garnering increased interest because of their synthetic flexibility to incorporate a variety of cations, thereby altering their structure and properties. Aliovalent substitution is said to...

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Cite This Study

Phan et al. (2026) studied this question.

synapsesocial.com/papers/69a13571ed1d949a99abf5b3https://doi.org/10.1039/d5sc10183b
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