The addition of 3-isocyanatopropyltriethoxysilane and 2-aminonaphthalene in THF affords the title compound 1-(naphthalen-2-yl)-3-(3-(triethoxysilyl)propyl)urea 1. A determination of the crystal structure of this naphthyl urea reveals the occurrence of strong intermolecular N-H···O hydrogen bonds, giving rise to a 1D supramolecular ribbon, whose interactions have also been assessed by a Hirshfeld surface analysis. The propensity of 1 to sense halide ions by intramolecular trapping through N-H···Hal bonding was also investigated by UV-vis spectroscopy and fluorescence measurements.
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Abderrahim Khatyr
Isabelle Jourdain
Michael Knorr
Molbank
SHILAP Revista de lepidopterología
Centre National de la Recherche Scientifique
TU Dortmund University
Institut UTINAM
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Khatyr et al. (Wed,) studied this question.
www.synapsesocial.com/papers/69a75d3bc6e9836116a26ed6 — DOI: https://doi.org/10.3390/m2129