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March 4, 2026High Energy Chemistry0 citations

Surface Modification of Polyurethane by Coating Deposition in a Dielectric Barrier Discharge in a Hexamethyldisilazane Vapor Atmosphere

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AIA. N. IvanovDSD. A. ShutovVRV. V. Rybkin

Key Points

  • To investigate the feasibility of enhancing polyurethane surfaces through film deposition using dielectric barrier discharge.
  • Planar dielectric barrier discharge was utilized for film deposition.
  • Conditions included a hexamethyldisilazane atmosphere and helium as carrier gas.
  • Discharge frequency was maintained at 50 Hz and current at 3 mA during the process.
  • Surface morphology was analyzed using scanning electron microscopy.
  • Wettability was assessed using the contact angle method with polar and nonpolar liquids.
  • Film deposition resulted in the formation of an organosilicon coating on the polyurethane surface.
  • The surface wettability of the treated polyurethane was significantly higher than that of the untreated substrate.
  • Morphological analysis showed a distinct modification in surface characteristics after coating.

Abstract

The feasibility of using a planar dielectric barrier discharge for film deposition on the surface of polyurethane substrates has been shown. The following conditions have been used: an atmospheric-pressure discharge generated in a flow chamber in a hexamethyldisilazane atmosphere at a fixed flow rate; carrier gas, helium; discharge frequency, 50 Hz; discharge current, 3 mA; apparent power transferred to the discharge, 24 VA; and deposition time, 30–1200 s. The surface morphology and elemental composition of the deposited film have been studied by scanning electron microscopy and energy-dispersive X-ray spectroscopy. Surface wettability has been determined by the contact angle method involving droplet imaging. Analysis of the elemental composition of the deposited coatings has shown the formation of an organosilicon film. The use of the contact angle method employing polar (distilled water) and nonpolar liquids (diiodomethane, glycerol) has shown that the wettability of the deposited coatings is higher than that of the untreated substrate.

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Cite This Study

Ivanov et al. (2026) studied this question.

synapsesocial.com/papers/69a7cd2ad48f933b5eed93c4https://doi.org/10.1134/s0018143925601125
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