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March 4, 2026ACS Applied Nano Materials0 citations

Multifunctional Electrospun Polyacrylonitrile/Polyaniline/Cellulose Nanocrystal/Reduced Graphene Oxide Membranes Enable Bacterial Inactivation and Lead Removal for Decentralized Water Treatment

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JSJaqueline J. S. SoaresRJRaynara M. S. JacovoneDRDebora F. Rodrigues

Key Points

  • The aim is to develop a portable membrane that filters water and inactivates pathogens while removing heavy metals like lead.
  • Developed a membrane using polyacrylonitrile, polyaniline, cellulose nanocrystals, and reduced graphene oxide.
  • Optimized graphene oxide concentration for enhanced membrane properties.
  • Tested the membrane's performance using low-voltage electrochemical methods.
  • Achieved a 7-log reduction of E. coli and Bacillus subtilis at 3 V.
  • Removed 76% of lead from spiked water samples.
  • Improved water quality by reducing nitrate, phosphate, and turbidity.

Abstract

In developing countries and rural areas, access to safe drinking water is a pressing issue that necessitates portable treatment solutions. This study describes the development of a portable conductive membrane capable of filtering and inactivating waterborne pathogens, removing lead (Pb (II)), and improving water quality parameters using a low-voltage current. A membrane composed of polyacrylonitrile (PAN) and polyaniline (PANI) integrated with cellulose nanocrystals (CNC) and graphene oxide (GO) nanosheets (PAN@PANI/CNC/GO) was first optimized to determine the optimal GO concentration. The incorporation of these nanomaterials improved the wettability, increased hydraulic conductivity, and enhanced mechanical properties. The PAN@PANI/CNC/GO membrane with 0.5% GO was subsequently reduced using the eco-friendly l-(+)-ascorbic acid (LAA) method, resulting in a PAN@PANI/CNC/rGO membrane with enhanced conductivity. The reduced PAN@PANI/CNC/rGO exhibited an electrical conductivity of 1.83 ± 0.01 S/cm, enabling an efficient electrochemical performance at low voltages. At a voltage of 3 V, the membrane achieved a 7-log reduction of Escherichia coli and Bacillus subtilis. In addition, it effectively reduced nitrate, phosphate, and turbidity concentrations and removed 76% of Pb (II) from real water samples spiked with 0.1 mg/L of Pb (II), confirming its multifunctional removal capability. These results highlight the PAN@PANI/CNC/rGO membrane as a promising point-of-use (POU) nanocomposite material for integrated bacterial inactivation, heavy metal removal, and overall improvement in water quality.

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Cite This Study

Soares et al. (2026) studied this question.

synapsesocial.com/papers/69a7cd6ed48f933b5eed9b5chttps://doi.org/10.1021/acsanm.5c05857
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