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March 4, 2026ACS Applied Materials & Interfaces0 citations

Calcium-Overloaded Multifunctional Nanoparticles for Synergistically Enhanced Photothermal and Chemotherapy and Immune Activation in Triple-Negative Breast Cancer

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XYXiaoyu YangNZNing ZhaoQZQihang Zhao

Key Points

  • This research aims to develop a multifunctional nanoparticle platform for enhanced treatment of triple-negative breast cancer.
  • Developed CaO@C@PTX@TG nanoparticles for combined photothermal and chemotherapy.
  • Assessed the release of calcium ions alongside drug delivery.
  • Evaluated the effectiveness of the platform in vivo and in vitro.
  • The nanoparticle system effectively inhibited tumor growth and metastasis.
  • Demonstrated synergistic effects in promoting apoptosis and enhancing immune response.
  • Induced immunogenic cell death under light activation.

Abstract

Triple-negative breast cancer (TNBC) is a highly invasive subtype characterized by high recurrence rates and the absence of specific therapeutic targets, resulting in limited treatment efficacy and immune insensitivity. Nanoparticle-based photothermal therapy holds promise due to its selective tumor heating and minimal invasiveness; however, its effectiveness is constrained by limited biocompatibility and localized heat transfer. To address these challenges, a multifunctional therapy utilizing CaO@C@PTX@TG nanoparticles was developed for TNBC treatment. This platform combines multiple mechanisms, with the CaO@C core enabling photothermal and chemothermal conversion while simultaneously releasing calcium ions. In parallel, paclitaxel (PTX) enhances chemotherapy synergy. The TG modification improves nanoparticle biocompatibility and supports efficient drug release within target cells. Under light activation, the platform induces calcium-overload, generating synergistic effects with photothermal therapy, promoting apoptosis and enhancing the antitumor immune response through immunogenic cell death (ICD). In vivo and in vitro experiments demonstrated that the CaO@C@PTX@TG system effectively inhibited tumor growth and metastasis. This approach integrates thermotherapy, photothermal therapy, chemotherapy, calcium-overload and immune activation, presenting an effective treatment strategy for TNBC.

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Cite This Study

Yang et al. (2026) studied this question.

synapsesocial.com/papers/69a7cdf0d48f933b5eeda503https://doi.org/10.1021/acsami.6c01149
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