Printing Hybrid, Interdigitated Back-Contact Solar Cells

Interdigitated back-contact solar cells were fabricated entirely with inkjet printing. poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS), TiO2, and metal lines were printed on a textured silicon substrate with only one inkjet printer. No vacuum deposition or diffusion of a back surface field is needed for the printed IBC solar cell. Adding co-solvent to the PEDOT:PSS and passivation of the Si surface significantly reduced the losses and enhanced the short-circuit current, Jsc, and, as a result, improved the fill factor and efficiency of the devices. The thickness of the PEDOT:PSS layer is approximately half a micrometer measured by profilometer, which is thicker than the optimal range typically reported; there is still a best short-circuit current, Jsc, of 19.2 mA/cm2. To further improve the performance of the devices, an anti-reflective coating on the front side is required. Also, an improved metal contact ink is needed to improve the contact resistance between the PEDOT:PSS layer and the metal contact. The initial performance of all printed cells are compared to conventionally fabricated devices.