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March 10, 2026ChemNanoMat0 citations

Air Cathode Built From Rice Husk Derived Air Plasma Exposed SiO 2 @Al‐Doped Cadmium Oxide Employed in Aluminum Air Batteries and Supercapacitor

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NKN. KarthikeyanKVK. A. Vijayalakshmi

Key Points

  • This research aims to enhance air cathode performance in metal–air batteries using aluminum‐doped cadmium oxide and plasma-treated silicon dioxide.
  • Utilized air plasma treatment on silicon dioxide derived from rice husks
  • Combined treated SiO2 with aluminum-doped cadmium oxide to form a composite
  • Evaluated specific capacitance, cyclic stability, and oxygen reduction reaction kinetics in the composite
  • Achieved a specific capacitance of 640 F g−1 with the composite
  • Coulombic efficiency of 99% and capacity retention of 94% over cycles
  • Displayed a discharge capacity of 33.33 mAh in an aluminum–air battery
  • Maintained open-circuit voltage of 1.12 V while powering an LED for 5 days

Abstract

This study aims to enhance air cathodes in metal–air batteries by integrating aluminum‐doped cadmium oxide with plasma‐treated silicon dioxide. SiO 2 , extracted from rice husks, undergoes direct current glow discharge plasma treatment to improve surface properties, structural stability, and conductivity. Plasma treatment significantly enhances the SiO 2 surface, yielding a high specific capacitance of 640 F g −1 , improved catalytic activity, enhanced cyclic stability (coulombic efficiency of 99% and capacity retention of 94%), and increased hydrophilicity. When employed as the air cathode in an aluminum–air battery, the composite demonstrates efficient oxygen reduction reaction (ORR) kinetics, a discharge capacity of 33.33 mAh, and stable long‐term performance, successfully powering a light‐emitting diode (LED) for 5 days with an open‐circuit voltage of 1.12 V.

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Cite This Study

Karthikeyan et al. (2026) studied this question.

synapsesocial.com/papers/69af956970916d39fea4ce81https://doi.org/10.1002/cnma.202500424
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