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March 13, 2026ChemistrySelect0 citations

Synergistic Approach by Acid and Tightly Focused Optical Ray Induction for Amyloid Formation From Lysozyme

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DIDidarul IslamMIMd. Hafizul Islam

Key Points

  • To investigate the combined effects of acidic conditions and laser trapping on amyloid formation from lysozyme.
  • Irradiated a 10 mg/mL HEWL solution with an 800 nm laser at 600 mW for 30 minutes.
  • Measured Thioflavin T fluorescence to confirm amyloid fibril formation.
  • Assessed light scattering to evaluate protein aggregation.
  • Conducted photoluminescence lifetime measurements for structural analysis.
  • Utilized transmission microscopy to visualize fibrillar structures.
  • Observed enhanced Thioflavin T fluorescence indicating significant amyloid formation.
  • Detected increased light scattering confirming protein aggregation under the experimental conditions.
  • Photoluminescence measurements showed a shift from sub-nanosecond to several-nanosecond lifetimes during aggregation.
  • Transmission microscopy revealed well-ordered fibrillar assemblies post-irradiation.

Abstract

ABSTRACT Laser trapping provides a powerful noncontact approach for manipulating biomolecules and probing protein aggregation processes with high spatial precision. In this study, we demonstrate near‐infrared (NIR) laser trapping‐induced amyloid fibril formation from hen egg white lysozyme (HEWL) under acidic conditions (pH H 2). A 10 mg/mL of HEWL solution in 0.1% HCl was irradiated with an 800 nm continuous‐wave laser at 600 mW for 30 min. Thioflavin T (ThT) fluorescence exhibited a pronounced intensity enhancement and characteristic green emission, confirming the formation of β‐sheet‐rich amyloid structures. Simultaneously, increased light scattering of the trapping laser indicated protein aggregation. Photoluminescence lifetime measurements revealed a transition from sub‐nanosecond to several‐nanosecond lifetimes, further supporting amyloid formation. Transmission microscopy showed ordered fibrillar assemblies following irradiation. These findings highlight the synergistic role of acidic conditions and optical trapping in accelerating amyloid formation, providing a tunable platform to study protein misfolding relevant to neurodegenerative diseases.

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Cite This Study

Islam et al. (2026) studied this question.

synapsesocial.com/papers/69b3ad1302a1e69014ccf603https://doi.org/10.1002/slct.202505175
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