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March 14, 2026Chemical Communications0 citations

Visible-Light-Driven Photoreductive Complete Degradation of Sulfur Hexafluoride under Ambient Conditions

HZHu ZhangYCYi-Ming ChenSZSheng-Ye Zhang

Key Points

  • The research aims to investigate the complete degradation of sulfur hexafluoride using visible light.
  • Utilized visible-light irradiation with potassium tert-butoxide in dimethylformamide.
  • Conducted reactions under ambient conditions.
  • Monitored the cleavage process of S–F bonds.
  • Achieved complete defluorination of sulfur hexafluoride.
  • Electron injection was shown to weaken S–F bonds effectively.
  • Intermediates were produced that underwent stepwise cleavage.

Abstract

Visible-light irradiation with potassium tert-butoxide in dimethylformamide enables complete defluorination of sulfur hexafluoride under ambient conditions. Electron injection weakens the S–F bonds, producing intermediates that undergo stepwise cleavage. The process...

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Cite This Study

Zhang et al. (2026) studied this question.

synapsesocial.com/papers/69b4fb8db39f7826a300bd3ahttps://doi.org/10.1039/d6cc00483k
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