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March 15, 2026Semiconductors0 citations

Structural, Optical and Electrochemical Properties of Sn-doped ZnO Nanoparticles: Effect of Doping Concentration

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ADA. DineshLCL. Bruno ChandrasekarPSP. Shunmuga Sundaram

Key Points

  • This research investigates how varying tin doping concentrations affect the properties of zinc oxide nanoparticles and their supercapacitor performance.
  • Synthesized tin-doped ZnO nanoparticles with varying doping concentrations.
  • Examined crystallite size, strain, and texture coefficients.
  • Analyzed optical properties using luminescence spectrum techniques.
  • Tested specific capacitance using cyclic voltammetry and galvanostatic charge-discharge methods.
  • Doping with tin reduces crystallite size and increases dislocation density.
  • Optical bandgap is lower in tin-doped nanoparticles compared to undoped ones.
  • Supercapacitor performance shows enhanced specific capacitance due to tin doping.
  • Capacitive current contribution is significantly increased with doping.

Abstract

Chemically prepared tin-doped zinc oxide (Sn-doped ZnO) nanoparticles are prepared with different doping concentrations of tin. The crystallite size, strain, and texture coefficients are examined. The addition of tin reduces the crystallite size and enhances the dislocation density of the material. The optical bandgap of tin-doped nanoparticles is lower than undoped nanoparticles. The UV emission, near band edge emission and zinc vacancies are observed in the luminescence spectrum. The prepared nanoparticles are used as the electrode material in the supercapacitors. The cyclic voltammetry and galvanostatic charge-discharge techniques are employed to examine the specific capacitance of the material. The specific capacitance is notably enhanced due to the doping of tin. The capacitive and diffusive current contributions are evaluated and the doping enhances the capacitive current contribution. The prepared tin-doped electrode material is an excellent candidate for supercapacitor applications.

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Cite This Study

Dinesh et al. (2026) studied this question.

synapsesocial.com/papers/69b64d48b42794e3e660e1aehttps://doi.org/10.1134/s1063782625603292
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