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Solvated electron-driven hydroamination of olefins | Synapse

March 18, 2026Open Access

Solvated electron-driven hydroamination of olefins

Key Points

The research aims to explore a transition metal-free method for hydroamination of olefins using solvated electrons.
Utilized granulated lithium to generate solvated electrons
Employed sonication in 2-methyltetrahydrofuran (2-MeTHF) for electron generation
Conducted intermolecular hydroamination reactions
Successfully achieved hydroamination of olefins
Showed effectiveness without using traditional transition metal catalysts

Abstract

We report a transition metal-free method for the intermolecular hydroamination of olefins using solvated electrons, generated in situ from granulated lithium under sonication in 2-methyltetrahydrofuran (2-MeTHF).

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Authors

A

Anietie W. Williams

K

Kerry Gilmore

Journals

Organic & Biomolecular Chemistry

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Institutions

University of Connecticut

References and Citations

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Cite this study

Williams et al. (Thu,) studied this question.

www.synapsesocial.com/papers/69ba428e4e9516ffd37a2f70 — DOI: https://doi.org/10.1039/d5ob01936b