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March 26, 2026The Proceedings of Mechanical Engineering Congress Japan0 citationsOpen Access

Predictive Modeling of Mechanical Strength Degradation in Polycarbonate via Hydrolysis Under Temperature, Humidity, and Time-Dependent Conditions

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TMTakashi MOMIYAMATYTakahiro YoshimotoHNHidekazu NAKATAKUMA

Key Points

  • The research aims to predict how mechanical strength in polycarbonate degrades over time due to hydrolysis influenced by environmental factors.
  • Selected four types of hydrolyzable resins for analysis.
  • Measured mechanical strength over time under controlled high-temperature and high-humidity conditions.
  • Derived a new prediction formula based on vapor pressure and temperature.
  • Identified significant degradation in mechanical strength due to hydrolysis in high humidity.
  • Developed a prediction formula that accurately represents the strength degradation.
  • Confirmed that temperature and vapor pressure are critical factors in deterioration.

Abstract

A variety of engineering plastics are widely used in electrical industrial products. Compared to metals, these plastics generally have shorter product lifetimes and lower mechanical strength, making it important to predict their functional lifetime. Resins such as Polycarbonate (PC) or Polybutylene Terephthalate (PBT), which contain ester bonds in their polymer main chain, are prone to hydrolysis caused by water vapor, resulting in strength degradation. In this study, four types of hydrolyzable resins—including polycarbonate and polybutylene terephthalate—were selected, and their time-dependent mechanical strength were measured following exposure to high-temperature and high-humidity conditions. Based on the results, a new prediction formula for strength degradation was derived using vapor pressure and temperature as independent parameters.

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Cite This Study

MOMIYAMA et al. (2025) studied this question.

synapsesocial.com/papers/69c4ccebfdc3bde448918886https://doi.org/10.1299/jsmemecj.2025.s114-09
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