The complexity of Classical Marcus analysis for charge transfer state in organic photovoltaics

Key Points

• This research aims to analyze the complexities of classical Marcus theory in extracting charge transfer state properties in organic photovoltaics.
• Analyzed electroluminescence and sensitive external quantum efficiency spectra
• Applied classical Marcus theory to evaluate charge transfer states
• Investigated donor-acceptor pair interactions within organic photovoltaics
• Identified limitations in applying classical Marcus theory in practical scenarios
• Showed that current methods may underrepresent charge transfer state properties
• Suggested alternative approaches for improved analysis of charge transfer dynamics

Abstract