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April 3, 2026ACS Applied Materials & Interfaces1 citations

All-Oxide ITO/HZO/WO x Ferroelectric Tunnel Junctions with Oxygen-Engineered Interfaces for Highly Endurable Neuromorphic Computing

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SJSeungjoon JeongHSHuiseong ShinMCMyeongjae Choi

Key Points

  • To create a simple ferroelectric tunnel junction (FTJ) structure that enables stable switching for neuromorphic computing.
  • Developed a metal-ferroelectric-metal (MFM) FTJ with ITO/Hf0.5Zr0.5O2/WOx layers.
  • Engineered the interfacial properties by tuning the oxygen stoichiometry in WOx.
  • Implemented neural-network simulations based on conductance characteristics.
  • Achieved a resistance ratio of approximately 100.
  • Demonstrated switching endurance over 10^8 cycles.
  • Realized 64 well-resolved conductance states and robust analog weight modulation.

Abstract

Ferroelectric tunnel junctions (FTJs) are promising synaptic devices for neuromorphic computing owing to their compact two-terminal structure and ability to support multilevel conductance modulation. However, many FTJ synapses rely on complex multilayer stacks or additional insertion layers to stabilize interfacial transport, increasing device complexity and limiting scalability. Here, we demonstrate a structurally simple metal-ferroelectric-metal (MFM) FTJ based on an ITO/Hf0.5Zr0.5O2/WOx stack in which the interface and electrode properties are deliberately engineered to achieve stable switching without additional layers. By tuning the oxygen stoichiometry of the WOx bottom electrode, a controlled trap-rich interfacial region is formed that enables polarization-modulated trap-assisted tunneling. In addition, the use of an ITO top electrode redistributes the electric field across the junction, improving programming reliability and breakdown tolerance. As a result, the optimized FTJ exhibits a resistance ratio of ∼100, switching endurance exceeding 108 cycles, and 64 well-resolved conductance states. The device further demonstrates stable spike-dependent plasticity and reliable analog weight modulation suitable for neuromorphic operation. Neural-network simulations based on experimentally extracted conductance characteristics achieve 91.5% accuracy on the MNIST data set, highlighting the potential of simple MFM FTJ synapses for scalable neuromorphic and in-memory computing hardware.

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Cite This Study

Jeong et al. (2026) studied this question.

synapsesocial.com/papers/69cf5ecb5a333a821460d617https://doi.org/10.1021/acsami.6c00989
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