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An expression is derived for the equilibrium free energy difference between two configurations of a system, in terms of an ensemble of finite-time measurements of the work performed in parametrically switching from one configuration to the other. Two well-known identities emerge as limiting cases of this result.
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Christopher Jarzynski (Mon,) studied this question.
www.synapsesocial.com/papers/69d68e73a70b37cec732f770 — DOI: https://doi.org/10.1103/physrevlett.78.2690
Christopher Jarzynski
Physical Review Letters
University of Washington
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