Broadband Coherent Raman Scattering: Excitation Architectures and Operating Regimes

Coherent Raman scattering (CRS) techniques such as coherent anti-Stokes Raman scattering (CARS) provide chemically specific vibrational contrast with signal levels far exceeding spontaneous Raman scattering (SpRS). Extending these to broadband excitation enables multiplex detection across wide spectral regions, including the fingerprint region, CH-stretch bands and high-frequency vibrational modes. This review provides a structured overview of excitation architecture for broadband CRS, ranging from low-energy oscillator schemes to energy-scalable platforms. The discussion is organized along key design parameters, including spectral bandwidth, excitation intensity, and probe delay, which jointly determine the accessible operating regimes. Rather than representing competing methods, the reviewed architectures are presented as a complementary toolbox for application-driven spectroscopy in chemically reactive environments and complex biological systems. In addition, a representative OPCPA-based implementation is presented as a platform demonstration to illustrate accessible operating regimes, single-shot stability, and multiplex detection capability under realistic experimental conditions.