Micellar-Colloidal Iron Oxyhydroxide-Integrated Hybrid-Composites Photocatalysts for Orthogonal Rhodium/Cobalt-Mediated NAD⁺/NADH Cycling and Mediator-Free Boronic Acid Hydroxylation

Key Points

• The aim is to develop visible-light-driven photocatalysts for sustainable cofactor regeneration and organic transformations.
• Synthesis of iron oxyhydroxide-integrated composite frameworks
• Utilization of visible-light for photocatalytic processes
• Evaluation of NAD⁺/NADH cycling and boronic acid hydroxylation effectiveness
• Successful development of photocatalysts demonstrating cofactor regeneration
• Effective mediation of organic transformations under visible light
• Significant improvement in hydroxylation reactions with boronic acids

Abstract