Highly Enantioselective Oxidation Reactions Using a Tetradentate Mn(II) Catalyst Based on ( S , S )-1,2-Diaminocyclohexane

Key Points

• To evaluate the effectiveness of a chiral Mn(II) catalyst for highly enantioselective oxidation reactions.
• Application of a chiral Mn(II) catalyst derived from trans-1,2-diaminocyclohexane.
• Oxidation of mono-, di-, and trisubstituted olefins.
• Oxidation of various organosulfur(II) compounds.
• Achieved high enantioselectivity in oxidation reactions.
• Successfully oxidized a range of olefins and organosulfur compounds.

Abstract