Preparation and Properties of Electro-Blown Spinning Erythritol-Based Coaxial Phase Change Fibers

Phase change thermal storage fibers with high latent heat have attracted significant attention in thermal management and heat storage. Through fiber encapsulation, shape-stable phase change materials can be prepared, thereby expanding their applications. In this study, electro-blown spinning was utilized to prepare phase change materials (PCM) using erythritol, with polyethylene oxide (PEO) as the carrier material. Coaxial thermal storage fibers encapsulating the phase change materials were prepared using polyvinyl alcohol (PVA) and polyvinylpyrrolidone (PVP). The results indicate that the composite fibers have a smooth surface, uniform and smooth morphology, a maximum latent heat of 223.01 J/g, as well as excellent thermal stability. The coaxial fibers exhibit a distinct core–shell structure, with the coaxial fibers encapsulated with PVA as the shell material, demonstrating a high latent heat of 118.62 J/g, a residual rate of 93.81% after heating, and excellent thermal performance. The encapsulation efficiency is 53%, effectively addressing the issue of erythritol leakage. The research results provide valuable guidance for the efficient preparation of erythritol coaxial thermal storage fibers.