Arsenic contamination, mainly in the arsenate (As(V)) form, continues to pose a serious threat to groundwater quality worldwide due to its long-term stability and toxicity at very low levels. Herein, we demonstrate, for the first time, a three-dimensional graphene oxide-based nanocomposite composed of Cu nanoparticle-doped, amino-functionalized UiO-66 (Cu/UiO-66-NH2) anchored on a graphene oxide framework (Cu/UiO-66-NH2@GO) as a novel and efficient nanosorbent for the rapid removal of As(V) in groundwater-like solutions. The nanocomposite was characterized by SEM and HRTEM to confirm the hybrid structure and by XRD, N2 adsorption–desorption isotherms, and XPS to investigate crystallinity, porosity, and surface chemistry. The derived material exhibited a highly dispersed morphology and performed rapid arsenate solid-phase extraction to attain equilibration within 10 min and was effective for a wide pH range of 2–11. The best fit for the kinetic profiles was provided by the pseudo-second-order model. Interestingly, the maximum adsorption capacity of 747.9 mg g−1 at pH 6.8 was achieved, demonstrating the benefits of the complementary pairing of dispersive GO sheets and Zr-MOF adsorption domains with Cu-derived active sites. Mechanistically, the enhanced uptake is ascribed to a combination of effects, including electrostatic pre-concentration, ligand exchange, and inner-sphere complexation at metal-oxo nodes; spectroscopic analysis (XPS and FTIR) suggests that the majority of arsenate is immobilized via a strong Zr-O-As bond at coordinatively unsaturated Zr centers, which is in line with t-ZrO2-like surface domains formed within the nanocomposite. The embedded GO support inhibits further framework interpenetration and enhances active site availability and mass transport, leading to fast and high-capacity arsenate capture in groundwater samples with related conditions. Taken together, this work presents a powerful design concept that integrates unique GO-supported, Cu-modified UiO-66-NH2 with Zr-O binding motifs to afford high-rate remediation nanocomposites, providing an excellent platform for next-generation arsenate remediation materials.
Zainy et al. (Tue,) studied this question.