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April 20, 2026ACS Applied Polymer Materials0 citationsOpen Access

Thermal Actuation of Predesigned Asymmetric Liquid Crystal Elastomer Films

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YLYan-Ting LinCKChung-Yu KuoHMHan Ma

Key Points

  • The aim is to compare the thermal behavior of asymmetric and symmetric liquid crystal elastomer films.
  • Investigated the performance of photopolymerized liquid crystal elastomer films.
  • Conducted experiments under near-infrared (NIR) irradiation over multiple cycles.
  • Compared the displacement and movement of asymmetric and symmetric LCE films.
  • Asymmetric liquid crystal elastomer films exhibited significant displacement compared to symmetric ones.
  • The films bulged towards the light source, achieving up to 1.9 cm of movement under NIR.
  • Origami-inspired designs of asymmetric films enhanced the thermal actuation effect.

Abstract

Although numerous studies have explored asymmetric structures in the design of liquid crystal elastomers (LCEs), investigations comparing the differences between asymmetric and symmetric structures using the same LCE composition are still limited. In this study, we investigate the distinctive thermally driven behavior of LCEAs with asymmetric structures and compare their performance with symmetric counterparts. The photopolymerized liquid crystal elastomer (LCE) film exhibits asymmetric bulging toward the light source, enabling directional control of thermal actuation. Only asymmetric LCE films produce significant displacement; under seven cycles of NIR irradiation, the film moves up to 1.9 cm. Moreover, asymmetric origami-inspired designs further enhance thermally induced motion, providing new concepts for soft robotics and industrial automation.

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Cite This Study

Lin et al. (2026) studied this question.

synapsesocial.com/papers/69e5c2d003c2939914028ceahttps://doi.org/10.1021/acsapm.6c00389
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