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April 22, 2026Polymer Engineering and Science0 citations

Reactive Extrusion of Waste Coating Powders With Recycled Polypropylene: Rheological and Mechanical Properties

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ABAbdelwahab BoukheitNYNoëllie YllaÉCÉloi Chamczyk

Key Points

  • This work aims to develop fully recycled materials by blending polypropylene with coating powders and to understand their interaction and properties.
  • Blending polypropylene with waste coating powders through reactive extrusion.
  • Conducting physico-chemical characterization using techniques such as FTIR, DSC, and rheology.
  • Investigating the mechanical properties and processing behavior of the blends.
  • Achieved a gel fraction of up to 0.64 in the polymer matrix.
  • Altered rheological and mechanical behavior due to the incorporation of coating powders.
  • Identified a threshold for coating powder content beyond which mechanical properties degrade.

Abstract

ABSTRACT Within the framework of circular materials strategies, this study explores the development of 100% recycled materials by blending polypropylene (PP), sourced from used paint buckets, with coating powders (CP) collected from construction sites. This work leverages an innovative recycling approach via reactive extrusion. The coating powders, primarily composed of epoxy/polyester resins and potentially containing fillers, pigments, and metallic particles, undergo crosslinking reactions when thermally processed into the PP matrix, achieving a gel fraction of up to 0.64. This study addresses two main challenges: (i) understanding the reaction mechanisms between the coating powder and polypropylene (in situ crosslinking), and (ii) investigating the structure–property relationships of the PP–CP blends, with emphasis on processing behavior and performance limitations. A thorough physico‐chemical characterization (FTIR, DSC, TGA, SEM/EDX, rheology, and solvent extraction) of the coating powders was performed to determine their composition and curing kinetics. The incorporation of coating powders induced measurable physical changes in the polymer matrix, including altered rheological and mechanical behavior, suggesting a plasticizing effect due to the non‐reacted CP fraction. A threshold CP content was identified, beyond which mechanical properties begin to degrade significantly.

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Cite This Study

Boukheit et al. (2026) studied this question.

synapsesocial.com/papers/69e864ec6e0dea528dde999ahttps://doi.org/10.1002/pen.70542
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