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April 24, 2026Polymer Chemistry0 citationsOpen Access

Recent progress in bulk polymerization: spatiotemporally discontinuous change of polymerization accompanied by phase separation

YSYasuhito SuzukiAMAkikazu Matsumoto

Key Points

  • The study aims to investigate the dynamics of bulk polymerization and its relationship with phase separation and spatiotemporal changes.
  • Analysis of polymerization reactions in bulk conditions
  • Observation of vitrification effects
  • Investigation of the Trommsdorff effect in polymerization
  • Identified critical link between polymerization acceleration and phase separation.
  • Demonstrated spatiotemporal heterogeneity during the polymerization process.
  • Observed significant vitrification impacting final polymer properties.

Abstract

Bulk polymerization converts liquid monomers into polymers via an exothermic reaction, often leading to vitrification and spatiotemporal heterogeneity, which is closely linked to the sudden reaction acceleration known as the Trommsdorff effect.

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Cite This Study

Suzuki et al. (2026) studied this question.

synapsesocial.com/papers/69eb092b553a5433e34b3c7fhttps://doi.org/10.1039/d6py00006a
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