Supercapacitors have garnered significant global interest due to their high power density, rapid charge‐discharge rates, and exceptional cycling stability. Among emerging electrode materials, bimetallic conductive metal‐organic frameworks (MOFs) are particularly notable for their efficient electronic and ionic charge transport and tunable structural properties. This review first elucidates the charge transport mechanisms in MOFs, including through‐space, through‐bond, and hopping charge transport. It then systematically examines key optimization strategies for enhancing their performance as electrode materials, including π ‐delocalization to achieve superior conduction, redox‐boosted conductivity, and dimensional modulation. Furthermore, this review discusses the advanced applications of bimetallic conductive MOFs in supercapacitors, with a focus on structure‐property relationships. By offering in‐depth insights into the rational design of high‐performance electrodes using bimetallic conductive MOFs, this review provides valuable guidance for future research aimed at scalable and efficient energy storage solutions.
She et al. (Thu,) studied this question.