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April 29, 2026Journal of Vacuum Science & Technology A Vacuum Surfaces and Films1 citationsOpen Access

Anodic vacuum arc evaporation of graphite for depositing layers of tetrahedral amorphous carbon

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BSBert ScheffelOZO. ZywitzkiSSStefan Saager

Key Points

  • This research aims to develop a scalable method for depositing tetrahedral amorphous carbon (ta-C) layers using anodic vacuum arc evaporation.
  • Applied anodic vacuum arc evaporation to deposit ta-C layers with thicknesses of 1.3–2.2 μm at deposition rates up to 18 nm/s.
  • Utilized substrates with high heat capacity and interlayers to address previous adhesion issues.
  • Conducted nanoindentation tests and Raman spectrometry to analyze mechanical properties and sp3 content.
  • Achieved hardness values of 71 to 84 GPa and Young's moduli ranging from 717 to 862 GPa.
  • Detected sp3 content between 68% and 75% in the deposited layers.
  • Produced layers that are free of droplets and feature a very smooth surface.

Abstract

Anodic vacuum arc evaporation was applied to deposit ta-C layers with thicknesses of 1.3–2.2 μm at high deposition rates of up to 18 nm/s. Building on prior work that was limited to a thickness of 0.8 μm due to high heat flux and adhesion issues, substrates with a high heat capacity and adhesion-promoting interlayers were used. Nanoindentation tests revealed hardness values ranging from 71 to 84 GPa and Young’s moduli ranging from 717 to 862 GPa for these layers. Raman spectrometry revealed an sp3 content of 68% to 75%. The layers are free of arc-typical droplets and have a very smooth surface. These results demonstrate that anodic vacuum arc evaporation, when combined with targeted thermal management and interlayer design, provides a scalable method of producing ta-C coatings for challenging mechanical or chemical engineering applications.

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Cite This Study

Scheffel et al. (2026) studied this question.

synapsesocial.com/papers/69f1a08eedf4b468248071cbhttps://doi.org/10.1116/6.0005354
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