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Synapse
May 2, 20260 citations

Using Diffusely Charged Bridging Ligands to Maximize Single-Ion Anisotropy and Dipolar Coupling in Dinuclear ErCOT Molecular Magnets.

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MBMaximilian G. BernbeckAOAngelica P. OrlovaJRJeffrey D. Rinehart

Key Points

  • This research aims to enhance magnetic properties in dinuclear complexes by increasing single-ion anisotropy and dipolar coupling.
  • Studied the dinuclear complex [Bu using diffusely charged bridging ligands.
  • Measured magnetic anisotropy and dipolar coupling effects on the molecular magnets.
  • Demonstrated significant improvements in single-ion anisotropy and dipolar interactions.
  • Showed potential for higher dimensionality in molecular magnet structures.

Abstract

The building-block approach toward higher-dimensional molecular magnets is predicated on the tension between the goals of installing strong magnetic anisotropy while enhancing long-range magnetic cooperativity. We describe the dinuclear complex [Bu

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Cite This Study

Bernbeck et al. (2026) studied this question.

synapsesocial.com/papers/69f594ca71405d493afffa50https://doi.org/10.1021/acs.inorgchem.6c01168
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