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May 3, 2026Hydrogeology Journal0 citationsOpen Access

Hydrogeochemical characterisation of the Bushveld Complex (South Africa), through water sample analysis in a core-drilled well with circulating drilling fluid

RLRolene LubbeAAAmy Jane AllwrightSLStephanus Steyn de Lange

Key Points

  • This study aims to characterize the hydrogeochemical properties of the Bushveld Complex through water sample analysis despite contamination risks.
  • Conducted hydrogeochemical sampling during core drilling in the Bushveld Complex.
  • Implemented integrated analytical methods including chemistry, stable isotopes, and end-member mixing analysis (EMMA).
  • Analyzed water samples from various depths, distinguishing between shallow and deep sample characteristics.
  • Shallower samples (< 450 m) reflected the regional hydrogeochemical signature, with EMMA revealing up to 100% background groundwater.
  • Deeper samples (> 450 m) showed influence from drilling fluids, with a dominance of source water at depths, highlighting mixing effects.
  • Identified a calcium chloride water type at 450 mbgl with an electrical conductivity peak of approximately 8000 µS/cm.

Abstract

Abstract Hydrogeochemical sampling during core drilling in the Bushveld Complex, South Africa, as part of the Bushveld Complex Drilling Project (BVDP) funded by the International Continental Scientific Drilling Program (ICDP), is challenging due to contamination risks associated with circulating fluids, which can lead to the dismissal of valuable data. This study investigated pragmatic procedures and integrated analytical methods (chemistry, stable isotopes, and end-member mixing analysis (EMMA)) to collect and interpret data from a deep exploration well in the Bushveld Complex despite potential contamination. Findings showed that shallower samples ( 450 mbgl) were more influenced by the drilling fluids, quantifiable through EMMA, showing a clear shift towards source water dominance (e.g. up to 100% source water at 935 mbgl) suggesting potential mixing or displacement effects at depth. Furthermore, a distinct calcium chloride (CaCl 2 ) water type with a peak electrical conductivity (EC) of approximately 8000 µS/cm was identified at 450 mbgl, indicative of saline fracture flow. The study demonstrates that hydrogeochemical data can be obtained through the application of best practices and integrated analysis in challenging drilling environments. It highlights the critical need for consistent, validated, and standardised protocols for this process.

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Cite This Study

Lubbe et al. (2026) studied this question.

synapsesocial.com/papers/69f6e5618071d4f1bdfc60d2https://doi.org/10.1007/s10040-026-03080-9
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