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May 6, 2026Organic Letters0 citations

Photoinduced LMCT-Catalyzed Regioselective C(sp 3 )–H Functionalization of Boronates via a 1,2-Boryl Migration Pathway

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DLDong Sheng LiZDZhuan DuWHWen-Kai He

Key Points

  • The research aims to develop a method for regioselective C(sp3)–H functionalization of boronates.
  • Applied photoinduced LMCT catalysis for regioselective reactions.
  • Investigated a sequential hydrogen atom transfer.
  • Examined the 1,2-boryl migration pathway.
  • Enabled regioselective C(sp3)–H functionalization of boronates.
  • Achieved diverse functionalized boronates with good regioselectivity.
  • Demonstrated a step-economical route for functionalization.

Abstract

)-H alkylation and arylation of unactivated alkyl boronates. This method enables a step-economical route to diverse functionalized boronates with good regioselectivity. Mechanistic studies suggest that the reaction proceeds through a sequential hydrogen atom transfer and 1,2-boryl migration pathway.

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Cite This Study

Li et al. (2026) studied this question.

synapsesocial.com/papers/69fa8eca04f884e66b5311a1https://doi.org/10.1021/acs.orglett.6c01326
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