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May 6, 2026Annals of Work Exposures and Health0 citations

25 Accuracy and interferences associated with direct-on-filter quartz analysis of samples obtained from a brickworks, copper mine and gold mine

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ZLZaakir LambatJPJ M Du PlessisSPSonette du Preez

Key Points

  • The study aims to evaluate the accuracy of quartz analysis using FTIR spectrometers in different mining contexts.
  • Analyzed 44 RCS exposure samples from a brickworks, copper mine, and gold mine using FTIR and XRD.
  • Utilized the NIOSH Field Analysis of Silica Tool for assessing quartz levels.
  • Conducted XRD analysis on bulk samples to determine mineral content affecting quartz results.
  • Mean bias for quartz measurement was highest in copper mine (0.026 mg), followed by brickworks (−0.007 mg) and gold mine (0.002 mg).
  • Identified minerals, including muscovite and pyrophyllite, that interfere with quartz analysis.

Abstract

Abstract Background Numerous publications have demonstrated that potable Fourier Transform Infrared (FTIR) spectrometers can be used to perform direct-on-filter quartz analysis to obtain results quicker following respirable crystalline silica (RCS) exposure monitoring. This study analysed respirable crystalline silica (RCS) exposure samples from three commodities to test their influence on the quartz results obtained from a potable FTIR spectrometer. Methods Forty-four RCS exposure samples collected form a brickworks crushing area (n = 12), copper mine crushing area (n = 12) and gold mine tailings dam (n = 20) were analysed direct-on-filter using a PerkinElmer Spectrum 2 portable FTIR spectrometer and the NIOSH Field Analysis of Silica Tool (FAST). This was followed by X-ray diffraction (XRD) analysis using NIOSH 7500. Additionally, bulk samples from the copper mine and gold mine tailings dam were analysed using XRD (PANalytical X’Pert Pro) to identify minerals that could interfere with the quartz analysis. The accuracy of the FTIR analysis was assessed using Bland-Altman plots. Results The mean bias between the methods was the higher for the copper mine crusher dust (0.026 mg) compared to the brickworks (−0.007 mg) and the gold mine tailings dam dust (0.002 mg). Bulk samples contained minerals that are known to interfere with quartz analyses. The copper mine crusher sand contained 43% quartz, 17% muscovite and 6% talc, and the gold tailing dam sand contained 85% quartz and 4% pyrophyllite. Conclusions Portable FTIR spectrometers can be very useful to obtain timely results post-shift. However, users should be mindful of minerals in the sample that can interfere with quartz analysis.

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Cite This Study

Lambat et al. (2026) studied this question.

synapsesocial.com/papers/69fa989404f884e66b5323fdhttps://doi.org/10.1093/annweh/wxag024.082
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