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May 7, 2026Biomolecules0 citationsOpen Access

Activation of the Nrf2/ARE Pathway Attenuates BDE-47-Induced Immunotoxicity in RAW264.7 Macrophages

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QGQian GaoQDQingyuan DengZYZiying Yang

Key Points

  • This research explores the role of the Nrf2/ARE pathway in mitigating BDE-47-induced apoptosis and immunotoxicity in RAW264.7 macrophages.
  • Network toxicology analysis was performed to identify Nrf2 as a hub gene.
  • Molecular docking and dynamics simulations assessed interaction between BDE-47 and the Keap1-Nrf2 complex.
  • Experimental studies in RAW264.7 cells examined the effects of BDE-47 and Nrf2 activation.
  • Activation of the Nrf2/ARE pathway was observed following BDE-47 exposure.
  • Nrf2 knockdown intensified apoptosis and immune dysfunction, with higher pro-inflammatory cytokine production.
  • Nrf2 activation is critical for limiting BDE-47-induced cytotoxicity in macrophages.

Abstract

Polybrominated diphenyl ethers (PBDEs), widely used as brominated flame retardants, are known to exert persistent adverse effects on the immune systems of humans and other organisms. Previous studies have demonstrated that 2,2′,4,4′-tetrabromodiphenyl ether (BDE-47), a prevalent congener, induces apoptosis, impairs phagocytic function, and triggers aberrant immune-inflammatory reactions in RAW264.7 macrophages via the induction of elevated intracellular reactive oxygen species (ROS). However, the underlying regulatory mechanism remains unclear. The nuclear factor erythroid 2-related factor 2/antioxidant response element (Nrf2/ARE) signaling pathway is a key cellular defense system against oxidative stress. In this study, we investigated the role of the Nrf2/ARE pathway in BDE-47-induced macrophage immunotoxicity. Network toxicology analysis identified Nrf2 as a hub gene within the BDE-47-associated immunotoxicity network. Molecular docking and molecular dynamics simulations suggested a potential interaction between BDE-47 and the Keap1-Nrf2 complex, with moderate binding affinity. Experimental studies in RAW264.7 cells showed that BDE-47 exposure activated the Nrf2/ARE pathway, as evidenced by Nrf2 nuclear translocation and the differential upregulation of downstream genes (GCLC, GCLM, HO-1, NQO1, SOD1, and CAT). Importantly, Nrf2 knockdown via lentiviral shRNA or pharmacological inhibition with brusatol significantly exacerbated BDE-47-induced apoptosis and immune dysfunction, including enhanced pro-inflammatory cytokine production and impaired phagocytosis. These results demonstrate that Nrf2/ARE pathway activation represents an adaptive antioxidant response and contributes to limiting BDE-47-induced cytotoxicity and immune impairment in macrophages.

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Cite This Study

Gao et al. (2026) studied this question.

synapsesocial.com/papers/69fbe2f2164b5133a91a2482https://doi.org/10.3390/biom16050674
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