Using Xenon Difluoride and 2 LiAlOC (CF3) 34 as an Oxidant: From Organoxenonium Intermediates to (Fluoro-) Biphenyl Radical Cations

Puntos clave

• To evaluate the potential of the XeF2/2Li[Al(ORF)4] system as a deelectronator.
• Investigated the reaction system XeF2/2Li[Al(ORF)4] as an oxidant.
• Analyzed the generation of organoxenonium intermediates.
• Examined the formation of radical cations from substrates.
• Successful generation of radical cations from various substrates.
• Production of Xe(g) and LiF(s) as byproducts.