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May 7, 2026Journal of the American Chemical Society3 citations

Condensation Center Regulation in Donor–Acceptor Polymers Enables Dynamic Proton Reservoirs for Efficient H 2 O 2 Photosynthesis

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FQFanzhi QinCZChen ZhangDQDeyu Qin

Key Points

  • This research explores the regulation of condensation centers in donor–acceptor polymers for enhancing photosynthesis efficiency.
  • Investigated the impact of -CN incorporation on energy barriers.
  • Examined para-regulation effects on electron transfer rates.
  • Analyzed proton behavior across varying pH levels.
  • Found that condensation center regulation improved charge transfer behavior.
  • Demonstrated broad pH adaptability by maintaining stable proton levels during reactions.

Abstract

ORR. In addition, -CN incorporation and para-regulation effectively lower the rate-limiting energy barriers, strengthening interfacial electron transfer. Dynamic proton reservoir behavior further endows the system with broad pH adaptability, maintaining stable local proton levels throughout the reaction. This work highlights the importance of condensation center regulation in programming reactant activation and charge transfer behavior, providing a design principle for advanced COPs in artificial photosynthesis.

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Cite This Study

Qin et al. (2026) studied this question.

synapsesocial.com/papers/69fbefa3164b5133a91a39f6https://doi.org/10.1021/jacs.6c00799
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