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May 7, 2026Physical Chemistry Chemical Physics0 citations

Roaming dynamics in highly excited-state unimolecular and complex bimolecular reactions

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YFYanlin FuYHYong‐Chang HanDZDong Hui Zhang

Key Points

  • This research aims to explore the dynamics of roaming in unimolecular and bimolecular reactions.
  • Analysis of reaction pathways in highly excited-state molecules.
  • Comparison of roaming dynamics with traditional transition states.
  • Identification of unexpected molecular products formed during reactions.
  • Roaming mechanisms were observed to bypass traditional minimum-energy paths.
  • Unconventional molecular products were formed, indicating novel reaction pathways.
  • The study enhances the understanding of complex unimolecular and bimolecular reaction dynamics.

Abstract

Roaming has been established as an unconventional reaction pathway that produces unexpected molecular products by circumventing the minimum-energy path associated with traditional transition states. Since its initial identification in 2004,...

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Cite This Study

Fu et al. (2026) studied this question.

synapsesocial.com/papers/69fbefc0164b5133a91a3b9fhttps://doi.org/10.1039/d6cp00404k
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