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May 9, 2026Journal of Materials Research and Technology0 citationsOpen Access

A dual-nanoparticle architecture for enhanced strength–ductility synergy in Mo alloys at elevated temperatures

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HLHaolong LiuZCZhenwei ChenJLJinbao Long

Key Points

  • The study aims to improve the balance of strength and ductility in refractory Mo alloys at high temperatures using a dual-nanoparticle architecture.
  • Constructed a dual-nanoparticle architecture using solid-state doping with TiC and ZrC nanoparticles.
  • Created core-shell precursor powders and consolidated them to yield non-shearable nanoscale dispersoids.
  • Evaluated the mechanical properties of the Mo alloys at room temperature and elevated temperatures.
  • Achieved ultimate tensile strength of 1081 MPa with 17.1% elongation at room temperature.
  • At 1000 °C, the alloy exhibited 585 MPa strength and 44.7% elongation.
  • At 1400 °C, retained 497 MPa strength with 49.7% elongation, outperforming existing Mo-based alloys.

Abstract

Achieving a superior combination of strength and ductility in refractory metals at elevated temperatures, remains a longstanding challenge for applications under extreme service conditions. Here, this challenge is addressed through the construction of a dual-nanoparticle architecture in powder-metallurgical Mo alloys. Core–shell precursor powders were designed via a solid-state doping strategy using ex-situ TiC and ZrC nanoparticles (∼50 nm), which, after consolidation, produced two populations of non-shearable nanoscale dispersoids, namely semi-coherent TiC precipitates with an average size of 69 nm and in-situ formed ZrO 2 particles with an average size of 204 nm. The dual dispersoid architecture generates pronounced Zener pinning, leading to effective grain refinement and enhanced microstructural thermal stability. As a result, the alloy exhibits an ultimate tensile strength of 1081 MPa with an elongation of 17.1% at room temperature. More importantly, it retains an outstanding strength–ductility synergy at elevated temperatures, achieving 585 MPa with 44.7% elongation at 1000 °C and 497 MPa with 49.7% elongation at 1400 °C, outperforming previously reported Mo-based alloys. These results demonstrate that dual-nanoparticle engineering is an effective strategy for simultaneously improving strength, ductility, and thermal stability in Mo alloys, and provide a practical design route for refractory alloys intended for wide-temperature extreme-environment applications.

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Cite This Study

Liu et al. (2026) studied this question.

synapsesocial.com/papers/69fecf16b9154b0b82876327https://doi.org/10.1016/j.jmrt.2026.05.037
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