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May 9, 2026Angewandte Chemie International Edition1 citationsOpen Access

Circularly Polarized Luminescent and Melt‐Processable Copper(I)‐Organic Glasses Based on 2,2′‐Bis(diphenylphosphino)‐1,1′‐binaphthyl

ZFZeyu FanISIndranil SenRPRoman Pallach

Key Points

  • This research aims to develop and characterize copper(I)-organic glasses that exhibit circularly polarized luminescence.
  • Fabricated centimeter-sized monoliths and thin films through molding and thermal annealing.
  • Conducted solvent vapor treatment for recrystallization to observe changes in luminescent properties.
  • Developed BINAP-based copper(I) complexes with notable processability and distinct luminescent changes post-treatment.
  • Demonstrated potential applications in optoelectronic devices due to improvements in luminescent performance.

Abstract

(Cu→BINAP) CT (CT = charge transfer) equilibrium. Centimeter-sized monoliths and thin films can be fabricated by molding and thermal annealing, highlighting their excellent processability. Moreover, the glasses can be recrystallized by solvent vapor treatment, which triggers distinct changes in luminescent properties. These results establish BINAP-based copper(I) cyanide complexes as a versatile platform for the design of CPL-active metal-organic glasses and point to their promise in optoelectronic applications.

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Cite This Study

Fan et al. (2026) studied this question.

synapsesocial.com/papers/69fed17eb9154b0b82878e6fhttps://doi.org/10.1002/anie.9766332
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