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May 10, 2026Organic Letters0 citations

TFPN-Mediated Chemoselective Reduction of Carboxylic Acids to Aldehydes and Primary Alcohols

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DZDou ZhangQZQiuyi ZhengJZJunhua Zhang

Key Points

  • The aim is to provide a rapid and efficient method for reducing carboxylic acids to aldehydes and primary alcohols using TFPN.
  • Utilized TFPN for reduction of carboxylic acids to aldehydes and primary alcohols.
  • Conducted reactions under mild, open-flask conditions at room temperature.
  • Demonstrated practicality with gram-scale synthesis and late-stage modification.
  • Achieved excellent functional-group tolerance during the reaction.
  • Provided a more economical and sustainable alternative to traditional multistep reductions.

Abstract

) delivers primary alcohols. The reaction proceeds rapidly under mild, open-flask conditions at room temperature, with excellent functional-group tolerance. Its practicality and scalability are demonstrated through gram-scale synthesis and late-stage modification of complex bioactive molecules. This provides a versatile, economical, and sustainable alternative to conventional multistep reduction processes.

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Cite This Study

Zhang et al. (2026) studied this question.

synapsesocial.com/papers/6a00217ac8f74e3340f9c5e4https://doi.org/10.1021/acs.orglett.6c01253
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