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May 10, 2026ChemistrySelect0 citations

Room‐Temperature Ammonia Gas Sensor Based on TiO 2 Aerogel With Enhanced Surface Hydroxyl Density: Preparation and Performance

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JLJiran LiangYZYixuan ZhangYZYingfu Zhang

Key Points

  • This study aims to enhance the sensitivity of TiO2 aerogel in detecting ammonia gas at room temperature.
  • Used sol-gel method and ambient pressure drying to prepare TiO2 aerogel
  • Investigated the effect of water molar ratio in precursor solution on sensor performance
  • Measured response to NH3 concentrations of up to 50 ppm
  • At 19.7% water molar ratio, the sensor shows a significant response of 14.12 to 50 ppm NH3
  • Enhanced response linked to nitrogen adsorption on surface hydroxyl groups via hydrogen bonding
  • Achieved better response time compared to previously reported TiO2 aerogel sensors

Abstract

ABSTRACT Although TiO 2 aerogel has structural advantages, they often suffer from low sensitivity in NH 3 detection. To improve the response of ammonia (NH 3 ) sensing at room temperature (25°C), this study aims to increase the concentration of surface hydroxyl groups. The sol‐gel method and ambient pressure drying are used to prepare TiO 2 aerogel, and the influence of the molar ratio of water in the precursor solution is studied. The results show that when the water molar ratio was 19.7%, the TiO 2 aerogel sensor exhibits a significant response 14.12 to 50 ppm NH 3 . The enhanced sensing response is attributed to the adsorption of NH 3 onto the abundant surface hydroxyl groups via hydrogen bonding. And the aerogel framework provides active sites (e.g., –OH and oxygen vacancies) that favor NH 3 adsorption. This work provides a method to fabricate room‐temperature NH 3 sensors with improved performance using TiO 2 aerogels. Compared with previously reported TiO 2 aerogel NH 3 sensors, this work achieves a shortened response time. Despite long recovery time and humidity‐induced response suppression, the TiO 2 aerogel structure provides a foundation for future room‐temperature NH 3 sensors.

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Cite This Study

Liang et al. (2026) studied this question.

synapsesocial.com/papers/6a00217ac8f74e3340f9c642https://doi.org/10.1002/slct.73395
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