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May 10, 2026Angewandte Chemie International Edition0 citationsOpen Access

Outside Front Cover: Oxidation State Determines Solvent Structure Around a Manganese–Vanadium Polyoxometalate Water‐Oxidation Catalyst

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STSimon TippnerMRMoritz RemmersSMSebastian Mai

Key Points

  • The study aims to understand how oxidation states of manganese vanadium oxide affect solvent organization around a water oxidation catalyst.
  • Theoretical and experimental approaches used to analyze solvent mixtures.
  • Assessment of oxidation states and their impact on hydration shell organization.
  • Oxidation states significantly influence the structure of water-acetonitrile mixtures.
  • Different solvent arrangements affect the catalyst's reactivity and stability.

Abstract

In the Research Article e9168848, Carsten Streb, Leticia González, and co-workers report a combined theoretical and experimental study on the solvent environment around a molecular water oxidation catalyst. The oxidation states of molecular manganese vanadium oxide control the organization of water-acetonitrile solvent mixtures, and thereby, the hydration shell in the catalyst vicinity. These findings shed light on catalyst reactivity and stability.

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Cite This Study

Tippner et al. (2026) studied this question.

synapsesocial.com/papers/6a0021e6c8f74e3340f9ce45https://doi.org/10.1002/anie.2026-m0405083400
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