PulseExploreJournal ClubDebatesTrendingResearchersJournals
Instagram
HomeExploreJournal ClubTrending
Synapse
⌘+K
Synapse
May 17, 2026Journal of Materials Chemistry C0 citations

Tunable Negative and Low Thermal Expansion in Magnetic Calcite-Type Fe1-xCrxBO3 (x = 0.0, 0.14, 1.0) Borates: A Comprehensive In Situ Study

YBY.P. BiryukovAZAlmaz Linarovich ZinnatullinASAndrey P. Shablinskii

Key Points

  • The study aims to investigate the thermal expansion properties of Fe1-xCrxBO3 borates across different compositions.
  • Synthesis of polycrystalline and single-crystal samples using multi-step solid-state reaction and flux methods.
  • In situ refinement of crystal structures to assess thermal expansion characteristics.
  • Negative and low thermal expansion was observed in all compositions of Fe1-xCrxBO3 borates.
  • Compositions varied distinctly in their thermal properties, suggesting a tunable nature.

Abstract

Polycrystalline and single-crystal samples of calcite-type Fe1-xCrxBO3 borates (x = 0.0, 0.14, 1.0) were synthesised via multi-step solid-state reaction and flux methods, respectively. Crystal structures were refined using in situ...

Ask AI
Helpful
Bookmark
Share
View Full Paper

Cite This Study

Biryukov et al. (2026) studied this question.

synapsesocial.com/papers/6a095af37880e6d24efe0c55https://doi.org/10.1039/d6tc01009a
Ask AI
Helpful
Bookmark
Share
View Full Paper

Also Consider

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

  1. 1Magnetic Behaviour of Ba0.75 – xCaxLa0.30Fe12Co0.25Ti0.15O19 Competing Magnetic Nature in Compound by Using Facile Route Methodology2025
  2. 2Tailoring Bi1<sub>-x-y</sub>Ba<sub>x</sub>Fe<sub>y</sub>FeO<sub>3</sub> for desired properties: insights into structural, dielectric, and magnetic responses2024
  3. 3Crystal Structure and Spectroscopic Studies of Ba<sub><i>x</i></sub>Ca<sub>1–<i>x</i></sub>CO<sub>3</sub>: The Order–Disorder Phase Transition of Calcite2024
  4. 4Unraveling low thermal expansion of CrBO3 via atomic scale analysis: Flexible CrO6 octahedron vs rigid BO3 triangle group2025
  5. 5Electronic and magnetic properties of boron substituted CuFeO <sub>2</sub> delafossite oxide2024