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May 20, 2026Soft Matter0 citationsOpen Access

Modeling the Slow Arrhenius Process (SAP) in Polymers

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VGValeriy GinzburgOGOleg GendelmanRCR. Casalini

Key Points

  • The study aims to model the slow Arrhenius process in amorphous glass-forming polymers and its implications on relaxation behavior.
  • Utilized theoretical models to simulate relaxation processes in polymers.
  • Analyzed the relationship between structural α-relaxation and secondary relaxations.
  • Focused on the distinct slow Arrhenius behavior observed in amorphous glass-formers.
  • Identified a clear distinction between structural α-relaxation and secondary relaxations in polymers.
  • Demonstrated that the slow Arrhenius process significantly impacts the mechanical properties of polymers.

Abstract

Amorphous glass-forming polymers exhibit multiple relaxation processes, including the structural α-relaxation associated with the glass transition and faster secondary relaxations that typically follow Arrhenius behavior. Recently, a distinct slow Arrhenius...

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Cite This Study

Ginzburg et al. (2026) studied this question.

synapsesocial.com/papers/6a0d4f34f03e14405aa9a663https://doi.org/10.1039/d6sm00305b
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