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May 31, 2026RSC AdvancesOpen Access

Planar tetracoordinate oxygen stabilized within triel–chalcogen dicationic frameworks

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Authors

LMLeinner MottaJCJennifer CuellarWGWilliams García-Argote

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Overview

Cluster dications demonstrate planar tetracoordinate oxygen, highlighting stability in rigid frameworks.

Key Points

  • This research aims to explore the stability of planar tetracoordinate oxygen in dicationic clusters.
  • Identification of nine D4h dicationic clusters O©X4E42+ with X = Al, Ga, In and E = S, Se, Te.
  • Assessment of electrostatic embedding within a rigid triel–chalcogen scaffold.
  • All nine identified clusters are global minima.
  • Planar tetracoordinate oxygen is effectively stabilized within these clusters.

Cite This Study

Motta et al. (2026) studied this question.

synapsesocial.com/papers/6a1bd12d5783ba022b6fcba6https://doi.org/10.1039/d6ra04411e
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