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June 5, 2026BMC Chemistry1 citationsOpen Access

Pyrazolo-triazole/hydrazono ester EPMT as a mixed-type corrosion inhibitor for low-carbon steel in 0.5 M HCl: electrochemical, surface, and computational evidence

GEGhada G. El-BanaMSMostafa E. SalemAIAhmed Z. Ibrahim

Key Points

  • This research investigates the efficacy of EPMT as a corrosion inhibitor for low-carbon steel in acidic conditions.
  • Evaluated EPMT’s inhibition performance in 0.5 M HCl through electrochemical and surface analyses.
  • Utilized SEM and AFM to compare surface conditions of treated vs. untreated steel.
  • Applied DFT and MC methods to assess adsorption characteristics of EPMT on steel.
  • Achieved 93.78% and 93.11% inhibition at 300 ppm EPMT concentration.
  • SEM and AFM results indicated restored surface characteristics of steel in presence of EPMT.
  • Computational analyses confirmed strong adsorption characteristics consistent with mixed-type inhibition.

Abstract

, corresponding to 93.78% and 93.11% inhibition, respectively, at 300 ppm. SEM and AFM comparisons showed that the acid-roughened steel surface was restored toward the polished state in the presence of EPMT. The tabulated DFT descriptors and MC adsorption energies further support strong adsorption of EPMT on Fe(110), consistent with mixed physisorption-chemisorption and effective surface blocking. Overall, the combined gravimetric, electrochemical, surface, and computational results demonstrate that EPMT is an efficient inhibitor for low-carbon steel in 0.5 M HCl.

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Cite This Study

El-Bana et al. (2026) studied this question.

synapsesocial.com/papers/6a22672f763171746d545e64https://doi.org/10.1186/s13065-026-01857-3
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