Colloidal crystals are periodic arrays of monodisperse particles that exhibit optical stopbands, which can be experimentally observed as a Bragg reflection characterized by a specific Bragg wavelength and width. Precise control of these characteristic parameters is essential for applications in structural color materials, sensors, and tunable photonic crystals. Although the Bragg reflection wavelength can be widely tuned by adjusting the lattice spacing via changes in particle size and concentration, controlling the width over a wide range—such as through expansion—is challenging because it is intrinsically determined by the refractive index contrast between the colloidal particles and their surrounding medium. In this study, the Bragg reflection width of non-close-packed colloidal crystals immobilized in an elastomer film was successfully expanded by adjusting the photoinitiator concentration and ultraviolet light intensity for photopolymerization. Expansion was attributed to the superposition of Bragg reflections at different wavelengths, resulting from spatial variations in the lattice spacings of the non-close-packed colloidal crystals formed during photopolymerization. Owing to the solvent-free and highly flexible nature of the elastomer-immobilized, non-close-packed colloidal crystal film, the Bragg reflection wavelength was readily tuned by mechanical compression while maintaining the expanded Bragg reflection width, thereby advancing the practical applications of structural color materials.
Makino et al. (2026) studied this question.