Long-Term Strength Development and Microstructural Characteristics of High-Content Cemented Soil Under Seawater Exposure

High-content cemented soils are critical for modern geotechnical technologies (e.g., pre-bored precast piles), yet their long-term durability remains underexplored. This study investigates the 28- to 365-day mechanical and microstructural evolution of high-content cemented silty clay under freshwater and seawater curing via UCS, SEM, MIP, and XRD. Under freshwater, cement content directly dictated strength, with the 8:2 mix reaching 24.31 MPa at 365 days. However, marginal efficiency analysis confirmed diminishing returns for excessive binder, establishing the 7:3 ratio as the optimal baseline. Seawater exposure induced a biphasic response: a 4.6% early strength gain at 28 days, followed by severe degradation (a 23.5% drop at 365 days). Concurrently, the failure mode shifted to macroscopic “pseudo-ductility,” with peak strain increasing from 2.37% to 3.04%. Crucially, a micro–macro inconsistency emerged: although seawater physically refined the pore structure (micropore proportion doubled to 30.2% at 90 days) via expansive salts filling mesopores, macroscopic strength declined. XRD confirmed this degradation coincides with severe long-term alkaline buffer (Ca(OH)2) depletion. Consequently, lifecycle durability assessments for high-binder marine systems must not rely solely on physical metrics like porosity, but adopt a coupled multi-factor framework prioritizing chemical stability.