A Novel Cadmium-Containing Porphyrin-Based Metal-Organic Framework Enables Oxidation of Inert C(sp 3 )-H Bonds

Key Points

• The study aims to address the challenges of selectively oxidizing inert C(sp3)-H bonds using cadmium-based frameworks.
• Synthesize two-dimensional cadmium porphyrin metal-organic frameworks (MnTCPP(Cd) and others)
• Test the frameworks under mild oxidative conditions
• Evaluate selectivity and efficiency in C(sp3)-H bond oxidation
• The cadmium porphyrin frameworks enable selective oxidation of C(sp3)-H bonds efficiently
• The reaction conditions are mild, making them suitable for various applications
• Isostructural frameworks showed consistent catalytic activity.

Abstract